气相爆轰合成碳纳米材料的研究进展Research Progress on Synthesis of Carbon Nanomaterials by Gaseous Detonation
陈端花,李晓杰,闫鸿浩,王小红,王宇新
摘要(Abstract):
气相爆轰合成是一种新型的碳纳米材料制备方法,相对于其他碳纳米材料制备方法而言具有反应速度快、产物种类多、产量大、纯度高、操作简单和经济性高等优点,有利于促进碳纳米材料的工业化生产。为深入阐明气相爆轰法合成碳纳米材料的研究与发展状况,介绍了气相爆轰法合成所需仪器设备、实验流程、理论计算以及产物的表征方法等,整理归纳了气相爆轰法合成碳包覆纳米金属粒子、碳纳米球、碳纳米管、碳点和碳纳米胶囊等技术与方法,分析了合成产物的形貌、结构及性能特征,展望了气相爆轰下各种新型碳纳米材料的应用潜力与技术发展趋势,以期为合理设计、针对性优化、规模化合成纳米材料奠定理论基础。研究表明:爆轰合成应结合宏观的爆轰理论和微细观的粒子生长。当前借助爆轰波发动机与爆轰胞格结构研究热点,使宏观爆轰胞格与纳米材料微观合成过程构成联系是重点研究方向。然而,在研究爆轰合成粒子的生长机理时,聚集在微细尺度上的纳米粒子生长仍然也是一种跨尺度问题,有必要引入分子动力学和格子波尔兹曼计算方法加以解决。
关键词(KeyWords): 气相爆轰合成;碳纳米材料;冲击波;碳包覆纳米金属;碳纳米胶囊
基金项目(Foundation): 国家自然科学基金(12072067金属粉末的爆炸压焊及其机理研究、11672067爆炸焊接界面细观缺陷产生的力学机理研究、12172084碳点的气相爆轰扫掠法制取及其水基润滑剂抗磨减摩机制研究)~~
作者(Author): 陈端花,李晓杰,闫鸿浩,王小红,王宇新
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